Forward or backward? New pathways for protons in water or methanol
A collaborative ultrafast spectroscopy and ab initio molecular dynamics simulations study shows that proton vacancies in the form of hydroxide/methoxide ions are as relevant for proton transfer between acids and bases as hydrated excess protons, thus pointing for a clear demand for refinement of the microscopic picture for aqueous proton transport – in solution as well as in hydrogen fuel cells or transmembrane proteins – away from currently often assumed dominant role of hydrated excess protons.
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