Forward or backward? New pathways for protons in water or methanol

A collaborative ultrafast spectroscopy and ab initio molecular dynamics simulations study shows that proton vacancies in the form of hydroxide/methoxide ions are as relevant for proton transfer between acids and bases as hydrated excess protons, thus pointing for a clear demand for refinement of the microscopic picture for aqueous proton transport – in solution as well as in hydrogen fuel cells or transmembrane proteins – away from currently often assumed dominant role of hydrated excess protons.

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Molecular nanocarbons with mechanical bonds

Scientists have succeeded in synthesizing molecular nanocarbons with knots and catenanes by using a novel method in which silicon atoms are used. The epoch-making product of this research will pave the way to the development of new nanocarbon materials with complex geometric structures.

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The fast dance of electron spins

Metal complexes show a fascinating behavior in their interactions with light, which for example is utilized in organic light emitting diodes, solar cells, quantum computers, or even in cancer therapy. In many of these applications, the electron spin, a kind of inherent rotation of the electrons, plays an important role. Researchers succeeded in simulating the extremely fast spin flip processes that are triggered by the light absorption of metal complexes.

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Determining the activity of noble-metal-free catalyst particles

Chemists have developed a new method with which they can characterize individual noble-metal-free nanoparticle catalysts. The particles could be a cheap alternative to precious metal catalysts for obtaining hydrogen from water by means of electrolysis.

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This is how a 'fuzzy' universe may have looked

Scientists have found that the early universe, and the very first galaxies, would have looked very different depending on the nature of dark matter. For the first time, the team has simulated what early galaxy formation would have looked like if dark matter were ''fuzzy,'' rather than cold or warm.

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